原著論文 2012年度

論文2012年度 / 論文2013年度 / 論文2014年度 / 論文2015年度 / 論文2016年度

計画班A01 計画班A02 計画班A03 計画班A04


Y. Tsukatani, H. Yamamoto, J. Harada, T. Yoshitomi, J. Nomata, M. Kasahara, T. Mizoguchi, Y. Fujita, H. Tamiaki, “An unexpectedly branched biosynthetic pathway for bacteriochlorophyll b capable of absorbing near-infrared light”, Scientific Reports, 3, 1217 (2013)

H. Tamiaki, K. Azuma, Y. Kinoshita, R. Monobe, T. Miyatake, S. Sasaki, “Chemosensitive chlorophyll derivatives: optical detection of various amines by synthetic 3-trifluoroacetyl-131-deoxo-pyropheophorbides in solution”, Tetrahedron, 69, 8, 1987-1993 (2013)

M. Numata, D. Kinoshita, N. Hirose, T. Kozawa, H. Tamiaki, “Orthogonal polymer recognition based on semi-artificial helical polysaccharide”, Chem. Lett., 42, 3, 266-268 (2013)

Y. Kinoshita, M. Kunieda, Y. Mikata, H. Tamiaki, “Synthesis, crystal structure and electronic absorption of chlorophyll derivatives possessing a β-diketonate moiety at the C3 position”, Tetrahedron Lett., 54, 10, 1243-1246 (2013)

M. Numata, D. Kinoshita, N. Hirose, T. Kozawa, H. Tamiaki, Y. Kikkawa, M. Kanesato, “Controlled stacking and unstacking of peripheral chlorophyll units drives the spring-like contraction and expansion of a semi-artificial helical polymer”, Chem. Eur. J., 19, 5, 1592-1598 (2013)

H. Tamiaki, M. Xu, Y. Kinoshita, “Synthesis of oxo-, thioxo- and methylene-substituted bacteriochlorins by modifying chlorophyll-a and their electronic absorption in visible and near-infrared regions”, J. Photochem. Photobiol. A: Chem., 252, 60-68 (2013)

H. Tamiaki, N. Kosaka, Y. Kinoshita, “Metallation of a cyclic chlorophyll hetero-dyad and optical properties of synthetic metallo-dyad”, Res. Chem. Int., 39, 1, 221-232 (2013)

M. Numata, M. Takayama, S. Shoji, H. Tamiaki, “Microflow-driven temporal self-assembly of amphiphilic molecules”, Chem. Lett., 41, 12, 1689-1691 (2012)

T. Mizoguchi, J. Harada, H. Tamiaki, “Characterization of chlorophyll pigments in the mutant lacking 8-vinyl reductase of green photosynthetic bacterium Chlorobaculum tepidum”, Bioorg. Med. Chem., 20, 23, 6803-6810 (2012)

Y.-W. Wang, X.-F. Wang, J.-P. Zhang, Z. Hong, J. Kido, O. Kitao, T. Ikeuchi, H. Tamiaki, S. Sasaki, “Development of solar cells based on synthetic near-infrared absorbing purpurins 2: Use of fullerene and its derivatives as electron acceptors for favorable charge separation”, J. Phys. Chem. C, 116, 40, 21244-21254 (2012)

S. Machida, Y. Isoda, M. Kunieda, H. Tamiaki, “Synthesis and epoxide-opening reaction a 3-oxiranyl-chlorophyll derivative”, Tetrahedron Lett., 53, 46, 6277-6279 (2012)

J. Harada, T. Mizoguchi, Y. Tsukatani, M. Noguchi, H. Tamiaki, “A seventh bacterial chlorophyll driving a large light-harvesting antenna”, Scientific Reports, 2, 671 (2012)

Y. Kashiyama, A. Yokoyama, Y. Kinoshita, S. Shoji, H. Miyashita, T. Shiratori, H. Suga, K. Ishikawa, A. Ishikawa, I. Inouye, K. Ishida, D. Fujinuma, K. Aoki, M. Kobayashi, S. Nomoto, T. Mizoguchi, H. Tamiaki, “Ubiquity and Quantitative Significance of Chlorophyll Detoxification Catabolism Associated with Protistan Herbivory in Aqueous Ecosystems”, Proc. Natl. Acad. Sci., USA, 109, 43, 17328-17335 (2012)

S. Shoji, T. Hashishin, H. Tamiaki, “Construction of chlorosomal rod self-aggregates in the solid state on any substrates from synthetic chlorophyll derivatives possessing an oligomethylene chain at the 17-propionate residue”, Chem. Eur. J., 18, 42, 13331-13341 (2012)

Y. Kataoka, Y. Shibata, H. Tamiaki, “Supramolecular Energy Transfer from Photoexcited Chlorosomal Zinc Porphyrin Self-Aggregates to a Chlorin or Bacteriochlorin Monomer as Models of Main Light-Harvesting Antenna Systems in Green Photosynthetic Bacteria”, Bioorg. Med. Chem. Lett., 22, 16, 5218-5221 (2012)

H. Tamiaki, M. Xu, S. Machida, “Photoreduced deformylation of zinc chlorophyll-d derivative”, Chem. Lett., 41, 8, 820-821 (2012)

N. Takahashi, S. Shoji, H. Tamiaki, Y. Saga, “Self-assembly of zinc bacteriochlorophyll d derivatives possessing a triethoxysilyl group at the 17-propionate residue”, Bull. Chem. Soc. Jpn., 85, 9, 989-994 (2012)

T. Horibe, K. Nakagawa, T. Kusumoto, R. Fujii, R.J. Cogdell, M. Nango, H. Hashimoto, “Polarization angle dependence of stark absorption spectra of spirilloxanthin bound to the reconstituted LH1 complexes using LH1-subunits isolated from the purple photosynthetic bacterium Rhodospirillum rubrum”, Acta Biochim. Pol., 59, 97-100 (2012)

C. Uragami, E. Yamashita, A. Gall, B. Robert, H. Hashimoto, “Application of resonance Raman microscopy to in vivo carotenoid”, Acta Biochim. Pol., 59, 53-56 (2012)

M. Yoshizawa, R. Nakamura, O. Yoshimatsu, K. Abe, S. Sakai, K. Nakagawa, R. Fujii, M. Nango, H. Hashimoto, “Femtosecond stimulated Raman spectroscopy of the dark S1 excited state of carotenoid in photosynthetic light harvesting complex”, Acta Biochim. Pol., 59, 49-52 (2012)

M. Sugisaki, D. Kosumi, K. Saito, R.J. Cogdell, H. Hashimoto, “Generation of coherently coupled vibronic oscillations in carotenoids”, Phys. Rev. B, 85, 245408 (2012)

A.W. Roszak, V. Moulisova, A.D.P. Reksodipuro, A.T. Gardiner, R. Fujii, H. Hashimoto, N.W. Isaacs, R.J. Cogdell, “New insights into the structure of the reaction centre from Blastochloris viridis: evolution in the laboratory”, Biochem. J., 442, 27-37 (2012)

T. Ochiai, M. Nagata, K. Shimoyama, T. Kato, T. Asaoka, M. Kondo, T. Dewa, K. Yamashita, A. Kashiwada, S. Futaki, H. Hashimoto, M. Nango, “Two-Dimensional Molecular Assembly of Bacteriochlorophyll a Derivatives Using Synthetic Poly(ethylene glycol)-Linked Light-Harvesting Model Polypeptides on a Gold Electrode Modified with Supported Lipid Bilayers”, ACS Macro Letters, 1, 28-32 (2012)

M. Nagata, M. Amano, T. Joke, K. Fujii, A. Okuda, M. Kondo, S. Ishigure, T. Dewa, K. Iida, F. Secundo, Y. Amao, H. Hashimoto, M. Nango, “Immobilization and Photocurrent Activity of a Light-Harvesting Antenna Complex II, LHCII, Isolated from a Plant on Electrodes”, ACS Macro Letters, 1, 296-299 (2012)

Y. Maeda, H. Hashimoto, T. Nishioka, “Sulfur containing platinum(II) complexes with N-heterocyclic carbene ligands obtained by reactions of a hydrosulfido complex”, Dalton Trans., 41, 12038-12047 (2012)

Y. Maeda, H. Hashimoto, T. Nishioka, “Synthesis and Reactivity of a Platinum(II) Complex with Hydrosulfido Ligands Induced by a Chelated N-Heterocyclic Carbene Ligand”, Chem. Lett., 41, 145-147 (2012)

D. Kosumi, S. Maruta, T. Horibe, Y. Nagaoka, R. Fujii, M. Sugisaki, R.J. Cogdell, H. Hashimoto, “Ultrafast excited state dynamics of spirilloxanthin in solution and bound to core antenna complexes: identification of the S* and T1 states”, J. Chem. Phys., 137, 064505 (2012)

M. Kondo, K. Iida, T. Dewa, H. Tanaka, T. Ogawa, S. Nagashima, K.V. Nagashima, K. Shimada, H. Hashimoto, A.T. Gardiner, R.J. Cogdell, M. Nango, “Photocurrent and electronic activities of oriented-His-tagged photosynthetic light-harvesting/reaction center core complexes assembled onto a gold electrode”, Biomacromolecules, 13, 432-438 (2012)

K. Kanemoto, H. Matsuoka, Y. Ueda, K. Takemoto, K. Kimura, H. Hashimoto, “Displacement current induced by spin resonance in air-treated conjugated polymer diodes”, Phys. Rev. B, 83, 125201 (2012)

K. Kanemoto, A. Fukunaga, M. Yasui, D. Kosumi, H. Hashimoto, HirotakaTamekuni, Y. Kawahara, Y. Takemoto, J. Takeuchi, Y. Miura, Y. Teki, “Ultrafast photoexcitation dynamics of π-conjugated bodipy-anthraceneradical triad system”, RSC Advances, 2, 5150-5153 (2012)

K. Kanemoto, S. Domoto, Y. Ohta, A. Ogata, H. Hashimoto, “Spectroscopic investigation of charge injection process in the bulkheterojunction P3HT:PCBM solar cell”, Phys. Status Solidi C, 9, 2395-2398 (2012)

T. Kajikawa, S. Okumura, T. Iwashita, D. Kosumi, H. Hashimoto, S. Katsumura, “Stereocontrolled total synthesis of fucoxanthin and its polyene chain-modified derivative”, Org. Lett., 14, 808-811 (2012)

M. Hirotsu, Y. Shimizu, N. Kuwamura, R. Tanaka, I. Kinoshita, R. Takada, Y. Teki, H. Hashimoto, “Anion-controlled assembly of four manganese ions: structural, magnetic, and electrochemical properties of tetramanganese complexes stabilized by xanthene-bridged Schiff base ligands”, Inorg. Chem., 51, 766-768 (2012)

M. Hirotsu, K. Santo, H. Hashimoto, I. Kinoshita, “Carbon- and Sulfur-Bridged Diiron Carbonyl Complexes Containing N,C,S-Tridentate Ligands Derived from Functionalized Dibenzothiophenes: Mimics of the [FeFe-Hydrogenase Active Site”, Organometallics, 31, 7548-7557 (2012)

R. Fujii, M. Kita, Y. Iinuma, N. Oka, Y. Takaesu, T. Taira, M. Iha, R.J. Cogdell, H. Hashimoto, “Isolation and purification of the major photosynthetic antenna, fucoxanthin-Chl a/c protein, from cultured discoid germilings of the brown Alga, Cladosiphon okamuranus TOKIDA (Okinawa Mozuku)”, Photosynth. Res., 111, 157-163 (2012)

R. Fujii, M. Kita, M. Doe, Y. Iinuma, N. Oka, Y. Takaesu, T. Taira, M. Iha, T. Mizoguchi, R.J. Cogdell, H. Hashimoto, “The pigment stoichiometry in a chlorophyll a/c type photosynthetic antenna”, Photosynth. Res., 111, 165-172 (2012)


Masui, Y. Nabetani, H. Tachibana, D. A. Tryk, H. Inoue, “How is the water molecule activated on metalloporphyrins? Oxygenation of substrates induced through one-photon/two-electron conversion in artificial photosynthesis by visible light”, Faraday Disc., 155, 145-163 (2012)

Y. Tamaki, K. Watanabe, K. Koike, H. Inoue, T. Morimoto, O. Ishitani, “Development of highly efficient supramolecular CO2 reduction photocatalysts with high turnover frequency and durability”, Faraday Disc., 155, 115-127 (2012)

Y.Nishijima, K. Ueno, K. Murakoshi, H. Inoue, and H. Misawa, “Near-Infrared Plasmon-Assisted Water oxidation”, J. Phys. Chem. Lett., 3, 1248-1252 (2012)

Yohei Ishida, Dai Masui, Tetsuya Shimada, Hiroshi Tachibana, Haruo Inouei, Shinsuke Takagi, “The Mechanism of the Porphyrin Spectral Shift on Inorganic Nanosheets: The Molecular Flattening Induced by the Strong Host-Guest Interaction Due to the “Size-Matching Rule””, J. Phys. Chem. C, 116, 7879-7885 (2012)

Takaaki Eyama, Yuko Yogo, Takuya Fujimura, Dai Masui, Tetsuya Shimada, Hiroshi Tachibana, Haruo Inouei, Shinsuke Takagi, “Adsorption and stacking behavior of zwitterionic porphyrin on the clay surface”, Clay Minerals, 47, 243-250 (2012)

Ishida, Yohei; Masui, Dai; Tachibana, Hiroshi; Inoue, Haruo; Shimada, Tetsuya; Takagi, Shinsuke, “Controlling the micro-adsorption structure of porphyrin dye assembly on clay surfaces using the “size-matching rule” for constructing an efficient energy transfer system”, ACS Applied Materials & Interfaces, 4, 811-816 (2012)

Yohei Ishida, Tetsuya Shimada, Hiroshi Tachibana, Haruo Inouei, Shinsuke Takagi, “Regulation of the Collisional Self-quenching of Fluorescence in Clay/Porphyrin Complex by the Strong Host-guest Interaction”, J. Phys. Chem. A, 116, 12065-12072 (2012)

Won-Sik Han, Kyung-Ryang Wee, Hyun-Young Kim, Chyongjin Pac, Yu Nabetani, Daisuke Yamamoto, Tetsuya Shimada, Haruo Inouei, Heesung Choi, Kyeongjae Cho and Sang Ook Kang, “Hydrophilicity Control of Visible-Light Hydrogen Evolution and Dynamics of the Charge-Separated State in Dye/TiO2/Pt Hybrid Systems”, Chem. Eur. J,, 48, 15368-15381 (2012)

H. Isobe, M. Shoji, S. Yamanaka, Y. Umena, K. Kawakami, N. Kamiya, J.-R. Shen, K. Yamaguchi, “Theoretical Illumination of Water-inserted Structures of the CaMn4O5 Cluster in the S2 and S3 States of OEC of PS II: Full Geometry Optimizations by UB3LYP”, Dalton Trans., 41, 13727-13740 (2012)

Keisuke Saito, Yasufumi Umena, Keisuke Kawakami, Jian-Ren Shen, Nobuo Kamiya, and, “Deformation of chlorin rings in the photosystem II crystal structure”, Biochemistry, 51, 4290-4299 (2012)

S. Yamanaka, K. Kanda, T. Saito, Y. Umena, K. Kawakami, J.-R. Shen, N. Kamiya, M. Okumura, H. Nakamura, K. Yamaguchi, “Electronic and spin structures of the CaMn4O5 cluster in OEC of PSII refined to 1.9 A X-ray resolution”, Adv. Quantum Chem., 64, 121-187 (2012)

S. Yamanaka, T. Saito, K. Kanda, H. Isobe, Y. Umena, K. Kawakami, J.-R. Shen, N. Kamiya, M. Okumura, H. Nakamura, K. Yamaguchi, “Structure and Reactivity of the Mixed-Valence CaMn4O5(H2O)4 and CaMn4O4(OH)(H2O)4 Clusters at Oxygen Evolution Complex of Photosystem II. Hybrid DFT (UB3LYP and UBHandHLYP) Calculations”, Int. J. Quantum Chemistry, 112, 321-343 (2012)

T. Saito, S. Yamanaka, K. Kanda, H. Isobe, Y. Takano, Y. Shigeta, Y. Umena, K. Kawakami, J.-R. Shen, N. Kamiya, M. Okumura, M. Shoji, Y. Yoshioka, K. Yamaguchi, “Possible Mechanisms of Water Splitting Reaction Based on Proton and Electron Release Pathways Revealed for CaMn4O5 Cluster of PSII Refined to 1.9 A X-Ray Resolutio”, Int. J. Quantum Chemistry, 112, 253-276 (2012)

T. Noguchi, “Monitoring the reactions of photosynthetic water oxidation using infrared spectroscopy”, Biomed. Spectrosc. Imaging, 2, 115-128 (2013)

H. Suzuki, M. Sugiura, and *T. Noguchi, “Determination of the miss probabilities of individual S-state transitions during photosynthetic water oxidation by monitoring electron flow in photosystem II using FTIR spectroscopy”, Biochemistry, 51, 6776-6785 (2012)

K. Ido, S. Kakiuchi, C. Uno, T. Nishimura, Y. Fukao, T. Noguchi, F. Sato, *K. Ifuku, “The conserved His-144 in the PsbP Protein is important for the interaction between the PsbP N-terminus and the Cyt b559 subunit of photosystem II”, J. Biol. Chem., 287, 26377-26387 (2012)

*T. Noguchi, H. Suzuki, M. Tsuno, M. Sugiura, and C. Kato, “Time-resolved infrared detection of the proton and protein dynamics during photosynthetic oxygen evolution”, Biochemistry, 51, 3205-3214 (2012)

S. Kakiuchi, C. Uno, K. Ido, T. Nishimura, T. Noguchi, *K. Ifuku, F. Sato, “The PsbQ protein stabilizes the functional binding of the PsbP protein to photosystem II in higher plants”, Biochim. Biophys. Acta, 1817, 1346-1351 (2012)

H. Yamazaki, S. Igarashi, T. Nagata, M. Yagi, “Substituent effects on core structures and heterogeneous catalytic activities of MnIII(μ-O)2MnIV dimers with 2,2’:6’,2’’-terpyridine derivative ligands for water oxidation”, Inorg. Chem, 51, 3, 1530-1539 (2012)


S. Kawasaki, K. Akagi, K. Nakatsuji, S. Yamamoto, I. Matsuda, Y. Harada, J. Yoshinobu, F. Komori, R. Takahashi, M. Lippmaa, C. Sakai, H. Niwa, M. Oshima, K. Iwashina, and A. Kudo, “Elucidation of Rh-Induced In-Gap States of Rh:SrTiO3 Visible-Light-Driven Photocatalyst by Soft X-Ray Spectroscopy and First-Principles Calculations”, J. Phys. Chem.C, 116, 24445-24448 (2012)

T. Sasamura, T. Osaki, T. Kameyama, T. Shibayama, A. Kudo, S. Kuwabata, and T. Torimoto, “Solution-phase Synthesis of Stannite-type Ag2ZnSnS4 Nanoparticles for Application to Photoelectrode Materials”, Chem. Lett., 41, 1009-1011 (2012)

M. Adachi and A. Kudo, “Effect of Surface Modification with Layered Double Hydroxide on Reduction of Nitrate to Nitrogen over BaLa4Ti4O15 Photocatalyst”, Chem. Lett., 41, 1007-1008 (2012)

S. Kawasaki, K. Nakatsuji, J. Yoshinobu, F. Komori, R. Takahashi, M. Lippmaa, K. Mase, and A. Kudo, “Epitaxial Rh-doped SrTiO3 thin lm photocathode for water splitting under visible light irradiation”, Appl. Phys. Lett., 101, 033910(1-4) (2012)

Q. Jia, K. Iwashina, and A. Kudo, “Facile Fabrication of an Efficient BiVO4 Thin Film Electrode for Water Splitting under Visible Light Irradiation”, Proc. Natl. Acad. Sci. USA, 109, 11564-11569 (2012)

T. Sasamura, K. Okazaki, A. Kudo, S. Kuwabata, and T. Torimoto, “Photosensitization of ZnO Rod Electrodes with AgInS2 Nanoparticles and ZnS-AgInS2 Solid Solution Nanoparticles for Solar Cell Application”, RSC Advances (RSC), 2, 552-559 (2012)

工藤昭彦, “光触媒を用いた人工光合成”, 理大 科学フォーラム,, 12, 10-13 (2012)

岩瀬顕秀,ジアチンシン,岩品克哉,工藤昭彦, “可視光水素製造のための新規光触媒系の開発”, セラミックス, 47, 664-668 (2012)

ジアチンシン,工藤昭彦, “Zスキーム型光触媒を用いた水の可視光分解反応”, 日本エネルギー学会誌, 91, 182-189 (2012)

K. Sakai, Hitoshi Sakai (1930-2008)”, Applied Geochemistry, 27, 1681-1687 (2012)

Masayuki Kobayashi, Shigeyuki Masaoka, and Ken Sakai, “Photoinduced Hydrogen Evolution from Water Based on a Z-Scheme Photosynthesis by a Simple Platinum(II) Terpyridine Derivative”, Angew. Chem. Int. Ed., 51, 30, 7431-7434 (2012)

Masaya Okamura, Masaki Yoshida, Reiko Kuga, Ken Sakai, Mio Kondo, and Shigeyuki Masaoka, “A Mononuclear Ruthenium Complex Showing Multiple Proton-Coupled Electron Transfer toward Multi-electron Transfer Reactions”, Dalton Trans., 41, 13081-13089 (2012)

Hoda A. El-Ghamry, Ken Sakai, Shigeyuki Masaoka, Kamal Y. El-Baradie, Raafat M. Issa, “Preparation, Characterization, Biological Activity and 3D Molecular Modeling of Mn(II), Co(II), Ni(II), Cu(II), Pd(II) and Ru(III) Complexes of Some Sulfadrug Schiff Bases”, Chin. J. Chem., 30, 4, 881-890 (2012)

K. Ueda, *H. Kato, M. Kobayashi, M. Hara, M. Kakihan, “Control of valence band potential and photocatalytic properties of NaxLa1-xTaO1+2xN2-2x oxynitride solid solutions”, J. Mater. Chem. A, 1, 3667-3674 (2013)


Sekizawa, K.; Maeda, K.; Domen, K.; Koike, K.; Ishitani, O., “Artificial Z-scheme Constructed with a Supramolecular Metal Complex and Semiconductor for the Photocatalytic Reduction of CO2”, J. Am. Chem. Soc., 135, 4596-4599 (2013)

Kentaro Teramura, Shoji Iguchi, Yuto Mizuno, Tetsuya Shishido, and Tsunehiro Tanaka, “Artificial Photosynthesis Using Typical Clays: Photocatalytic Conversion of CO2 in Water over Layered Double Hydroxides”, Angewandte Chemie International Edition, 51, 32, 8008-8011 (2012)

Yutaka Amao, Ayumi Hamano, Kaori Shimizu, “Development of artificial leaf for solar hydrogen production”, Energy Procedia, 29, 21-25 (2012)